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💧 Unit 3 · Intermolecular Forces & Properties 🏠 Unit Hub 🗂 Flashcards 🗺 Cheat Sheet ⭐ The Essentials 🎨 Visual Review 📝 MC Practice ✍️ SAQ Practice
💧 Unit 3 · 18–22% of Exam

Intermolecular Forces & Properties

The largest unit on the exam. London dispersion, dipole-dipole, and hydrogen bonding forces; solids, liquids, and gases; the ideal gas law and kinetic molecular theory; solutions and solubility; and spectroscopy.

12 topics
~28–38 class periods
4 Big Ideas covered
College Board aligned
← Back to AP Chemistry

Choose your study tool

Six ways to master Unit 3 — pick whichever fits how you like to study.

🗂
Flashcards
20 interactive flashcards covering every key term from Unit 3. Tap to flip, shuffle, and use keyboard arrows.
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🗺
Cheat Sheet
A one-page visual summary of Unit 3 — every key topic, term, and theme on a single screen.
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Essentials
The big ideas plus a searchable glossary of every vocabulary term you need to know for the exam.
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🎨
Visual Review
A slide-by-slide walkthrough of Unit 3 with diagrams of IMFs, phase diagrams, and gas behavior.
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📝
MCQ Practice
20 multiple-choice questions in College Board exam style — with full explanations of every answer.
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✍️
SAQ Practice
A short-answer question with model answers showing exactly how each part earns its point on the exam.
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Topics in Unit 3

Twelve topics from the College Board CED, in order — the most of any unit.

Topic 3.1
Intermolecular Forces
London dispersion, dipole-dipole, and hydrogen bonding forces, and how molecular structure determines which forces apply.
Topic 3.2
Properties of Solids
Crystalline solid types (ionic, metallic, covalent network, molecular) and amorphous solids, and how IMFs determine melting point and hardness.
Topic 3.3
Solids, Liquids, & Gases
Phase diagrams, vapor pressure, viscosity, and surface tension — all explained by relative IMF strength.
Topic 3.4
Ideal Gas Law
PV = nRT and its use in solving for pressure, volume, moles, or temperature of a gas sample.
Topic 3.5
Kinetic Molecular Theory
The assumptions behind ideal gas behavior, and how they connect temperature to average kinetic energy.
Topic 3.6
Deviation from Ideal Gas Law
Why real gases deviate from ideal behavior at high pressure and low temperature, due to molecular volume and IMFs.
Topic 3.7
Solutions & Mixtures
Solute, solvent, and the types of mixtures (homogeneous vs. heterogeneous).
Topic 3.8
Representations of Solutions
Particulate-level representations of solutions and concentration units, especially molarity.
Topic 3.9
Separation of Solutions & Mixtures
Chromatography and distillation as separation techniques based on physical property differences.
Topic 3.10
Solubility
"Like dissolves like" — how IMF compatibility between solute and solvent predicts solubility.
Topic 3.11
Spectroscopy & the Electromagnetic Spectrum
How different regions of the EM spectrum interact with matter, and what that reveals about molecular structure.
Topic 3.12
The Beer-Lambert Law
How absorbance relates to concentration, path length, and molar absorptivity — the basis of spectrophotometric analysis.

About Unit 3

Unit 3 is the largest unit on the AP Chemistry exam, and it's where the molecular shapes and polarities you predicted in Unit 2 finally pay off. Intermolecular forces — much weaker than the covalent and ionic bonds from Unit 2 — determine almost every macroscopic property you can observe: boiling point, viscosity, surface tension, and solubility. You'll also model gas behavior with the ideal gas law and kinetic molecular theory, learn why real gases deviate from ideal behavior, and study solutions, solubility, and spectroscopy.

This unit is roughly 18–22% of the AP Chem exam — nearly a quarter of all test questions — and spans 28–38 class periods, by far the longest unit. Expect IMF-based reasoning to show up constantly on both the multiple-choice and free-response sections.

The College Board ties Unit 3 to four Big Ideas — more than any other unit:

Big Idea SAP
Structure & Properties — IMF type and strength predict physical properties
Big Idea SPQ
Scale, Proportion & Quantity — the ideal gas law connects molecular behavior to measurable quantities
Big Idea TRA
Transformations — phase changes and dissolution as physical transformations driven by IMFs
Big Idea CE
Chemical Effects — electrostatic attraction underlies every intermolecular force
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