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🔗 Unit 2 · Molecular & Ionic Compound Structure & Properties 🏠 Unit Hub 🗂 Flashcards 🗺 Cheat Sheet Essentials 🎙 Podcast 🎨 Visual Review 📝 MC Practice ✍️ SAQ Practice

AP Chemistry Unit 2 Cheat Sheet

A one-page visual summary of Molecular & Ionic Compound Structure & Properties — every key topic, term, and theme you need to know for the exam, on a single screen.

← Back to Unit 2 hub

The basics

What it covers: How atoms combine — bonding types, Lewis structures, resonance, formal charge, and VSEPR-predicted molecular shape and hybridization.

Exam weight: About 7–9% of the AP Chemistry exam.

The big question: How does electron behavior (transfer, sharing, or delocalization) determine the structure and properties of a compound?

Big Ideas covered: Structure & Properties (SAP), Chemical Effects (CE), Scale, Proportion & Quantity (SPQ).

Key topics at a glance

Types of Chemical Bonds

Ionic (metal + nonmetal, electron transfer), covalent (nonmetal + nonmetal, electron sharing), metallic (metal + metal, delocalized electron sea).

Intramolecular Force & Potential Energy

Shorter, stronger bonds sit at the minimum of a potential energy curve. Triple > double > single bond in both energy and shortness.

Ionic Solids

Lattice energy increases with higher ionic charge and smaller ionic radius — explains why MgO has a much higher melting point than NaCl.

Metals & Alloys

The electron sea model explains conductivity, malleability, and ductility. Alloys mix in other elements to change hardness or corrosion resistance.

Lewis Diagrams

Satisfy the octet rule for main-group atoms. Count total valence electrons, place bonds and lone pairs.

Resonance & Formal Charge

Formal charge = valence e⁻ − nonbonding e⁻ − (bonding e⁻ ÷ 2). The best structure minimizes formal charges, closest to zero.

VSEPR

Electron domains repel to minimize repulsion. Lone pairs > bonding pairs in space — this bends and compresses molecular angles.

Hybridization

sp (linear), sp² (trigonal planar), sp³ (tetrahedral). Single bonds = 1 sigma; double = 1 sigma + 1 pi; triple = 1 sigma + 2 pi.

The key terms you must know

Key themes to remember

Common exam traps